Welcome to our LIVE coverage of this Champions League clash. Kick-off is at 7.45pm UK time, but we'll be here from an hour beforehand with the latest team news and pre-match build-up.

Full time it's finished NAPOLI 2-0 VILLARREAL, and Napoli sucure their first win in Europe's premier competition for 21 years. It was deserved. The Azzurri defended well in the second half, and although Villarreal may point to a couple of penalty decisions, they failed to create any great chances throughout the 90 minutes.

There are 4 minutes of added on time, De Sanctis has the ball in his hands.

From the free kick Napoli try and hold the ball in the corner before Mascara is adjudged to foul Zapata.

Mascara wins a free kick right by the corner flag in Villarreal's half.

The corner is too close to De Sanctis who collects well.

Sub Perez has made a difference. His mazy run down the right wins another corner for Villarreal.

Napoli make their third and final sub. Lavezzi is replaced by Santana. Villarreal have also made a double sub, Wakaso and Perez on for De Guzman and Senna.

Musacchio heads the corner well over.

A deflected Rossi shot wins a corner for Villarreal.

The game has become 'bitty' with both teams conceding fouls.

Napoli break before Inler is cynically fouled by Rossi. A challenge that signals his frustration with tonights action. Cani is also booked for protesting the penalty decision against Nilmar.

Villarreal appeal for a penalty as Nilmar is hit from behind by Zuniga. The referee signals that the Colombian won the ball. They've been given before though.

Napoli enjoy a brief spell of possession before Zuniga miss places a pass.

Villarreal continue to press, but Cannavaro has been a rock in the Napoli defence as he headers clear another Villarreal cross.

Napoli take off their other goal scorer. As Hamsik is replaced by Mascara, as the pressure mounts on the home side.

Zapata finds himself unmarked on the right of the Napoli area, his pull back finds Rossi whose first first time shot is blocked, the rebound comes to Nilmar who tries an acrabatic kick but slices it wide.

Rossi tries to play Nilmar through in the Napoli area, but an outstrteched Cannavaro just cuts out the pass. The yellows are building pressure though.

Nilmar finds space down the left inside the Napoli area, he cuts back onto his right foot, but blazes his shot high and wide.

The free kick is again hit straight into the wall by De Guzman.

Rossi again wins a free kick on the edge of the area. Turning Cannavaro before he is pulled back. The already booked Cannavaro can consider himself lucky to escape a second yellow.